SUPELCO Astec CHIRALDEX A-TA手性氣相色譜柱 毛細管柱
Supelco（色譜科）位于美國賓夕法尼亞州，是Sigma-Aldrich集團下屬的子品牌，Supelco一直通過提供更新的，更可靠的色譜產(chǎn)品和來幫助色譜工作者來解決問題，其涉及的領(lǐng)域和行業(yè)有環(huán)境、食品、飲料、政府、醫(yī)藥、化工等

SUPELCO Astec CHIRALDEX A-TA手性氣相色譜柱 毛細管柱
 

• CD Type: α (alpha)
• Derivative: Trifluoroacetyl
• Temp. Limits: -10 °C to 180 °C (isothermal or programmed)

    Incorporates a phase consisting of a 2,6-di-O-pentyl-3-trifluoroacetyl derivative of α-cyclodextrin.

    Trifluoroacetylation of the 3 position hydroxyl groups after pentylation of the 2,6 hydroxyl groups creates a phase with high selectivity for oxygen containing analytes in the form of alcohols, ketones, acids, aldehydes, lactones, and halogenated compounds.

Features: 

• Separates the widest variety of enantiomers
• Separates the greatest number of enantiomers
• Gamma more selective than beta form
• Unique retention behavior
• Extraordinary versatility and chiral selectivity

Analytes:

Useful for homologous series of:

• Amino acids (primary, secondary, aromatic and aliphatic)
• Amines (primary, secondary, cyclic, aromatic and halogenated)
• Amino alcohols
• Alkanes, hydrogenated alkanes
• Alcohols (aliphatic and aromatic)
• Acids (halogenated and hydroxy)
• Esters (aromatic, aliphatic, hydroxy, di-ester)
• DiolsLactonesKetones
• Phthalides
• Sulfoxides

Mechanism Observations:

• Strong dipole-dipole interactions
• Longer alkyl chain; greater retention; increase in enantioselectivity up to C4/C5
• Halogens known to favor cavity interaction

   Dipole-dipole interactions are commonly identified in the mechanism of separation for TA phases. In a homologous series of alkane enantiomers, identical alpha values are observed regardless of chain length or branching indicating only 1 or 2 carbons may be contributing to chiral recognition. Alpha values are greatly affected by size and polarity of the head group. Functional groups like epoxides, amino alcohols and alcohols can dictate the cyclodextrin selection. Aldehydes, carboxylic acids and epoxides separate better on the gamma while alcohols, alcohol amines and other linear molecules separate better on the beta derivative.

SUPELCO Astec CHIRALDEX A-TA手性氣相色譜柱 毛細管柱 訂貨信息：

Product #	Description
73002AST	Astec CHIRALDEX A-TA 毛細管氣相色譜柱 L × I.D. 20 m × 0.25 mm, df 0.12 μm
73003AST	Astec CHIRALDEX A-TA 毛細管氣相色譜柱 L × I.D. 30 m × 0.25 mm, df 0.12 μm
73004AST	Astec CHIRALDEX A-TA 毛細管氣相色譜柱 L × I.D. 40 m × 0.25 mm, df 0.12 μm
73005AST	Astec CHIRALDEX A-TA 毛細管氣相色譜柱 L × I.D. 50 m × 0.25 mm, df 0.12 μm